Unusual Metal-Coordinated Zwitterionic P−C−N−C−N−C Phosphido Adducts
نویسندگان
چکیده
منابع مشابه
Unusual metal-coordinated zwitterionic P-C-N-C-N-C phosphido adducts.
Rare examples of homodinuclear zwitterionic Pd(II) and Pt(II) complexes with bridging, two-coordinate P{cyclo-CH(2)N(R)CHN(R)CH(2)} ligands (R = 4-FC(6)H(4)CH(2), C(6)H(5)CH(2)) have been characterized by single-crystal X-ray diffraction using synchrotron radiation. Short N-C distances and enlarged N-C-N bond angles support electron delocalization in the central N-C-N backbone.
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2010
ISSN: 0020-1669,1520-510X
DOI: 10.1021/ic1002308